MATERIAL SAFETY DATA SHEET

SECTION 1	 PRODUCT AND COMPANY IDENTIFICATION	
PRODUCT
Product Name:    LIGHT HEATING OIL
Product Description:	   Petroleum Hydrocarbons
Product Code: 		   708123-85
Intended Use:  		 Heating Oil

COMPANY IDENTIFICATION
Supplier:		MOBIL OIL AUSTRALIA PTY LTD 
 A.B.N. 88 004 052 984
12 Riverside Quay  
Southbank
Victoria  3006     Australia 

 24 Hour Environmental / Health Emergency Telephone	 1-800-023-005	
 Product Technical Information	 1-800-033-863	
 Supplier General Contact	 1-800-631-296	

SECTION 2	 HAZARDS IDENTIFICATION	

Hazard Classification:  HAZARDOUS SUBSTANCE.  NON-DANGEROUS GOOD.

Classified in accordance with Approved Criteria for Classifying Hazardous Substances NOHSC:1008 & according to Australian Dangerous Goods Code.

CLASSIFICATION:    |    Xn; R65  |    Xi; R38  |  

POISON SCHEDULE NUMBER:   S5 

AS1940 COMBUSTIBLE CLASS:  C1

PHYSICAL / CHEMICAL HAZARDS
   Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited.   Material can accumulate static charges which may cause an incendiary electrical discharge.

HEALTH HAZARDS
 Harmful: may cause lung damage if swallowed.  Irritating to skin.  May be irritating to the eyes, nose, throat, and lungs.

ENVIRONMENTAL HAZARDS
 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SAFETY PHRASE(S):  S2; Keep out of the reach of children.  S23; Do not breathe vapour / spray  S24; Avoid contact with skin.  S43; In case of fire use carbon dioxide (CO2), foam, dry chemical, or water fog.  S61; Avoid release to the environment. Refer to special instructions/safety data sheets.  S62; If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
 
Note:   This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. 

 SECTION 3	 COMPOSITION / INFORMATION ON INGREDIENTS	
 
This material is regulated as a preparation.

Reportable Hazardous Substance(s) or Complex Substance(s) 
 Name	 CAS#	 Concentration*	 Symbols/Risk Phrases	
 KEROSENE	 8008-20-6	 > 99 %	 R10, Xi;R38, Xn;R65	
  
Reportable Hazardous Constituent(s) Contained in Complex Substance(s) 
 Name	 CAS#	 Concentration*	 Symbols/Risk Phrases	
 ETHYL BENZENE	 100-41-4	 0.1 - 1%	 F;R11, Xn;R20	
 Naphthalene	 91-20-3	 0.1 - 1%	 Xn;R22, Xn;Carc. Cat. 3;R40	
  
 * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Other ingredients determined not to be hazardous up to 100%.

 SECTION 4	 FIRST AID MEASURES	

INHALATION
Remove from further exposure.  For those providing assistance, avoid exposure to yourself or others.  Use adequate respiratory protection.  If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance.  If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water.  Remove contaminated clothing.  Launder contaminated clothing before reuse.

EYE CONTACT
Flush thoroughly with water.  If irritation occurs, get medical assistance.

INGESTION
Seek immediate medical attention.  Do not induce vomiting.

NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis.  Treat appropriately.

PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Hydrocarbon Solvents/Petroleum Hydrocarbons- Skin contact may aggravate an existing dermatitis. 

SECTION 5	FIRE FIGHTING MEASURES	

EXTINGUISHING MEDIA
Appropriate Extinguishing Media:  Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

Inappropriate Extinguishing Media:  Straight streams of water

FIRE FIGHTING
Fire Fighting Instructions:  Evacuate area.  Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply.  Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA).   Use water spray to cool fire exposed surfaces and to protect personnel. 

Unusual Fire Hazards:  Combustible.  Hazardous material. Firefighters should consider protective equipment indicated in Section 8.

Hazardous Combustion Products:   Smoke, Fume, Aldehydes, Sulphur Oxides, Incomplete combustion products, Oxides of carbon

FLAMMABILITY PROPERTIES 
Flash Point [Method]:  >61C  (142F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air):   LEL:  0.7     UEL: 5.0
Autoignition Temperature:  N/D 

 SECTION 6	 ACCIDENTAL RELEASE MEASURES	

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material.  Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material.  See Section 5 for fire fighting information.  See the Hazard Identification Section for Significant Hazards.  See Section 4 for First Aid Advice.  See Section 8 for Personal Protective Equipment.
 
SPILL MANAGEMENT
Land Spill:  Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).  Stop leak if you can do so without risk.  Do not touch or walk through spilled material.  Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.  Recover by pumping or with suitable absorbent.

Water Spill:  Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).  Stop leak if you can do so without risk.  Confine the spill immediately with booms.  Warn other shipping.  Remove from the surface by skimming or with suitable absorbents.  Seek the advice of a specialist before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken.  For this reason, local experts should be consulted.  Note:  Local regulations may prescribe or limit action to be taken. 

ENVIRONMENTAL PRECAUTIONS
Large Spills:  Dyke far ahead of liquid spill for later recovery and disposal.  Prevent entry into waterways, sewers, basements or confined areas.

 SECTION 7	HANDLING AND STORAGE	

HANDLING
Avoid contact with skin.  Use proper bonding and/or earthing procedures. Prevent small spills and leakage to avoid slip hazard.   Material can accumulate static charges which may cause an electrical spark (ignition source).    

Static Accumulator:   This material is a static accumulator.

STORAGE
Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release.  Store in a cool, well-ventilated area.  Storage containers should be earthed and bonded.  Drums must be earthed and bonded and equipped with self-closing valves, pressure vacuum bungs and flame arresters.            

Material is defined under the National Standard [NOHSC:1015] Storage and Handling of Workplace Dangerous Goods.

 SECTION 8	 EXPOSURE CONTROLS / PERSONAL PROTECTION	

EXPOSURE LIMIT VALUES

Exposure limits/standards (Note: Exposure limits are not additive)

 Substance Name	Form	Limit/Standard	Note	Source	Year	
ETHYL BENZENE		STEL	543 mg/m3	125 ppm		Australia OELs	2005	
ETHYL BENZENE		TWA	434 mg/m3	100 ppm		Australia OELs	2005	
ETHYL BENZENE		STEL	125 ppm			ACGIH	2009	
ETHYL BENZENE		TWA	100 ppm			ACGIH	2009	
KEROSENE	Stable Aerosol.	TWA	5 mg/m3			ExxonMobil	2009	
KEROSENE	Vapour.	TWA	200 mg/m3			ExxonMobil	2009	
KEROSENE [as total hydrocarbon vapor]	Non-Aerosol	TWA	200 mg/m3		Skin	ACGIH	2009	
Naphthalene		STEL	79 mg/m3	15 ppm		Australia OELs	2005	
Naphthalene		TWA	52 mg/m3	10 ppm		Australia OELs	2005	
Naphthalene		STEL	15 ppm		Skin	ACGIH	2009	
Naphthalene		TWA	10 ppm		Skin	ACGIH	2009	

NOTE: Limits/standards shown for guidance only.  Follow applicable regulations.

Biological limits

Substance Name	Specimen	Sampling Time	Limit	Determinant	Source	
ETHYL BENZENE	End-exhaled air	Not Applicable		ETHYL BENZENE	ACGIH BELs	
ETHYL BENZENE	Urine	End of shift at end of work wk	1.5 g/g creatinine	Mandelic acid	ACGIH BELs	
Naphthalene	Urine	End of shift at end of work wk		1-Hydroxypyrene, with hydrolysis (1-HP)	ACGIH BELs	

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.  Control measures to consider:
 Use explosion-proof ventilation equipment to stay below exposure limits.

PERSONAL PROTECTION
 
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation.  Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.  

Respiratory Protection:   If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate.  Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable.  Types of respirators to be considered for this material include: 
Particulate
No special requirements under ordinary conditions of use and with adequate ventilation. 

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.  Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection:   Any specific glove information provided is based on published literature and glove manufacturer data.  Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Nitrile,Viton
Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves.

Eye Protection:   If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection:    Any specific clothing information provided is based on published literature or manufacturer data.  The types of clothing to be considered for this material include:
 Chemical / oil resistant clothing if contact with material is likely.

Specific Hygiene Measures:   Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.

ENVIRONMENTAL CONTROLS
 See Sections  6,  7, 12, 13.

SECTION 9	 PHYSICAL AND CHEMICAL PROPERTIES	

Typical physical and chemical properties are given below.   Consult the Supplier in Section 1 for additional data.

GENERAL INFORMATION
Physical State:    Liquid 
Colour:   Clear (May Be Dyed)
Odour:   Petroleum/solvent
Odour Threshold:   N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C):    0.73   
Flash Point [Method]:     >61C  (142F) [ ASTM D-93]
Flammable Limits (Approximate volume % in air):   LEL:  0.7     UEL: 5.0  
Autoignition Temperature:  N/D 
Boiling Point / Range:    > 150C  (302F)
Vapour Density (Air = 1):   N/D
Vapour Pressure:   < 0.027 kPa (0.2 mm Hg) at 20 C
Evaporation Rate (N-Butyl Acetate = 1):   N/D
pH:   N/A
Log Pow (n-Octanol/Water Partition Coefficient):   > 3.5
Solubility in Water:   Negligible
Viscosity:   1 cSt (1 mm²/sec) at 40 C - 2.1 cSt  (2.1 mm²/sec) at 40 C
Oxidising properties:  See Sections 2, 15, 16.

OTHER INFORMATION
Freezing Point:   N/D
Melting Point:   N/A
Pour Point:      -32°C  (-25°F)     

 SECTION 10	 STABILITY AND REACTIVITY	

STABILITY:  Material is stable under normal conditions.

CONDITIONS TO AVOID:  Open flames and high energy ignition sources.

INCOMPATIBLE MATERIALS:   Halogens,  Strong Acids,  Alkalies,  Strong oxidisers

HAZARDOUS DECOMPOSITION PRODUCTS:  Material does not decompose at ambient temperatures.

HAZARDOUS REACTIONS:  Will not occur.

SECTION 11	 TOXICOLOGICAL INFORMATION	

Acute Toxicity

 Route of Exposure	 Conclusion / Remarks	
INHALATION		
Toxicity (Rat): LC50 > 5000 mg/m³	Minimally Toxic. Based on test data for structurally similar materials.	
Irritation: No end point data.	Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.	
		
INGESTION		
Toxicity (Rat): LD50 > 2000 mg/kg	Minimally Toxic. Based on test data for structurally similar materials.	
		
Skin		
Toxicity (Rabbit): LD50 > 2000 mg/kg	Minimally Toxic. Based on test data for structurally similar materials.	
Irritation (Rabbit): Data available.	Moderately irritating to skin with prolonged exposure. Based on test data for structurally similar materials.	
		
Eye 		
Irritation (Rabbit): Data available.	May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.	

CHRONIC/OTHER EFFECTS
             For the product itself:
 Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema.
Contains:
Kerosene:  Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in animal tests.  NAPHTHALENE:  Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain.
Ethylbenzene:  Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain.

Additional information is available by request.
 
IARC Classification:
The Following Ingredients are Cited on the Lists Below:
 
 Chemical Name	 CAS Number	 List Citations	
 ETHYL BENZENE	 100-41-4	 3	

--REGULATORY LISTS SEARCHED--	
 1 = IARC 1	 2 = IARC 2A	 3 = IARC 2B	

 SECTION 12	 ECOLOGICAL INFORMATION	

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY   
             Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

MOBILITY 
             More volatile component -- Highly volatile, will partition rapidly to air.  Not expected to partition to sediment and wastewater solids.
             High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land.  Expected to partition to sediment and wastewater solids. 

PERSISTENCE AND DEGRADABILITY
Biodegradation: 
             Majority of components --  Expected to be inherently biodegradable  
Atmospheric Oxidation: 
             More volatile component -- Expected to degrade rapidly in air

    

 
 
 SECTION 13	 DISPOSAL CONSIDERATIONS	
 
Disposal recommendations based on material as supplied.  Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. 

DISPOSAL RECOMMENDATIONS
 Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. 
 
 Empty Container Warning Empty Container Warning (where applicable):  Empty containers may contain residue and can be dangerous.  Do not attempt to refill or clean containers without proper instructions.  Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed.  Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations.  DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.  THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

 SECTION 14	 TRANSPORT INFORMATION	
LAND (ADG) :  Not Regulated for Land Transport

Footnote:  Special Provision AU02 applies if shipped in one or more compartments of a tank vehicle or portable tank transporting other refined petroleum products.

SEA (IMDG) 
Proper Shipping Name:   ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (KEROSENE)
Hazard Class & Division:    9
EMS Number:   F-A, S-F
UN Number:   3082
Packing Group:   III
Marine Pollutant:   Yes
Label(s):   9
Transport Document Name:      UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Kerosene), 9, PG III, (61°C c.c.), MARINE POLLUTANT

AIR (IATA) 
Proper Shipping Name:   ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (KEROSENE)
Hazard Class & Division:   9 
UN Number:   3082
Packing Group:   III
Label(s) / Mark(s):   9, EHS   
Transport Document Name:    UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (KEROSENE), 9, PG III

 SECTION 15	 REGULATORY INFORMATION	
 
Material is hazardous as defined by the Approved Criteria for Classifying Hazardous Substances NOHSC:1008.

CLASSIFICATION:   Harmful.  Irritant. The classification of this product is based all or in part on test data. 

Nature of Special Risk:  R65; Harmful: may cause lung damage if swallowed.  R38; Irritating to skin.

SAFETY PHRASE(S):  S2; Keep out of the reach of children.  S23; Do not breathe vapour / spray  S24; Avoid contact with skin.  S43; In case of fire use carbon dioxide (CO2), foam, dry chemical, or water fog.  S61; Avoid release to the environment. Refer to special instructions/safety data sheets.  S62; If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

Contains:  KEROSENE- UNSPECIFIED   

Product is not regulated according to Australian Dangerous Goods Code. 

Poison Schedule number allocated by the Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) established under the Therapeutic Goods Act.

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS

Complies with the following national/regional chemical inventory requirements:   AICS, DSL, EINECS, ENCS, KECI, PICCS, TSCA

 SECTION 16	 OTHER INFORMATION	

KEY TO ABBREVIATIONS AND ACRONYMS:
N/D = Not determined, N/A = Not applicable, STEL = Short-Term Exposure Limit, TWA = Time-Weighted Average

KEY TO THE RISK CODES CONTAINED IN SECTION 2 AND 3 OF THIS DOCUMENT (for information only):
 R20; Harmful by inhalation.
R22; Harmful if swallowed.
R38; Irritating to skin.
R40; Limited evidence of a carcinogenic effect.
R65; Harmful: may cause lung damage if swallowed.

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:
 Revision Changes:
Section 06: Protective Measures was modified.
Section 06: Notification Procedures - Header was modified.
Section 13: Empty Container Warning was modified.
Section 09: Physical State was modified.
Section 08: Hand Protection was modified.
Hazard Identification: Health Hazards was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release - Spill Management - Land was modified.
Section 06: Accidental Release - Spill Management - Water was modified.
Section 11: Chronic Tox - Component was modified.
Section 08: Exposure Limits Table was modified.
Section 12: Ecological Information - Acute Aquatic Toxicity was modified.
Section 14: Proper Shipping Name - Header was added.
Section 14: Proper Shipping Name was added.
Section 14: Hazard Class & Division - Header was added.
Section 14: Hazard Class was added.
Section 14: UN Number - Header was added.
Section 14: UN Number was added.
Section 14: Packing Group - Header was added.
Section 14: Packing Group was added.
Section 14: Label(s) - Header was added.
Section 14: Label(s) was added.
Section 14: EMS Number - Header was added.
Section 14: EMS Number was added.
Section 14: Transport Document Name - Header was added.
Section 14: Transport Document Name was added.
Section 14: Proper Shipping Name was added.
Section 14: Proper Shipping Name - Header was added.
Section 14: Hazard Class & Division - Header was added.
Section 14: Hazard Class was added.
Section 14: UN Number - Header was added.
Section 14: UN Number was added.
Section 14: Packing Group - Header was added.
Section 14: Packing Group was added.
Section 14: Label(s) - Header was added.
Section 14: Label(s) was added.
Section 14: Transport Document Name - Header was added.
Section 14: Transport Document Name was added.
Section 14: Marine Pollutant - Header was added.
Section 14: Marine Pollutant was added.
Section 14: IMO Technical Name - All was added.
Section 14: IATA Technical Name - All was added.
Section 14: IMO Technical Name - Close parenthesis was added.
Section 14: IATATechnical Name - Close parenthesis was added.
Section 14: IMO Technical Name - Open parenthesis was added.
Section 14: IATA Technical Name - Open parenthesis was added.
Section 14: ADG Footnote was added.
Describes under what criteria substance was classified. was added.
Australia AS1940 Combustible Class was added.
Australia AS1940 Combustible Class was added.
Australia Storage and Handling for combustible liquids statement NOHSC:1015 was added.
Section 14: Sea (IMDG) - Default was deleted.
Section 14: Air (IATA) - Default was deleted.
Section 01: AU Hazardous/Not Hazardous/May Be Hazardous was deleted.
Composition: Australia Refer to Regulatory Information Statement was deleted.

  
THIS SDS COVERS THE FOLLOWING MATERIALS:  LHO
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 The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate and reliable as of the date issued.  You can contact ExxonMobil to insure that this document is the most current available from ExxonMobil.  The information and recommendations are offered for the user's consideration and examination.  It is the user's responsibility to satisfy itself that the product is suitable for the intended use.  If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container.  Appropriate warnings and safe-handling procedures should be provided to handlers and users.  Alteration of this document is strictly prohibited.  Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted.  The term, "ExxonMobil" is used for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any affiliates in which they directly of indirectly hold any interest.

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DGN:  7073334XAU  (1011346)
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 Prepared By:          Exxon Mobil Corporation
                              EMBSI, Clinton NJ USA
Contact Point:       See Section 1 for Local Contact number

End of (M)SDS